| Role | Voice Part | Classification |
|---|---|---|
| Dutchess of Alba (Donna Cayetana) | Mezzo Soprano | L |
| Francisco Goya | Tenor | L |
| Maria Luisa, Queen of Spain | Soprano | F |
| Charles IV, King of Spain | Tenor | F |
| Martin Zapater (the writer Moratin) | Baritone | F |
| Manuel Godoy, the Prime Minister | Baritone | F |
| Leocadia | Mezzo Soprano | S |
| Tavern Singer | Tenor | S |
| A Maid, to the Dutchess | Mezzo Soprano | B |
| Major-Domo | Tenor | B |
| The Innkeeper | Bass | B |
| A Black-Boy (adopted by the Dutchess) | Mute Child | |
| The French Ambassador | Mute | |
| Two Ladies in Waiting (to the Dutchess) | Mute | |
| Don Basilio | Mute | |
| Minimum Chorus: 24 | ||
| Divisi: SATB |
Schedule C