| Role | Voice Part | Classification |
|---|---|---|
| Joan of Arc (the Maid) | Mezzo-Soprano | L |
| Charles VII, King of France | Tenor | F |
| Agnes Sorel, his Mistress | Soprano | F |
| Thibaut, Joan's Father | Bass | F |
| Dunois, a French Soldier | Baritone | F |
| Lionel, a Burgundian Soldier | Baritone | F |
| The Archbishop (the Cardinal) | Bass | F |
| Raymond, a young man in love with Joan | Tenor | S |
| Bertrand, an old peasant | Bass | S |
| A Soldier (Voyn) | Bass | B |
| Lore, a wounded soldier | Bass | B |
| An Angel voice (from the chorus) | Soprano | CB |
| Minimum Chorus: 48 | ||
| Divisi: SATB |
Schedule C